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Large-format scintillators
Clean Room at RMD
Micrograph of RMD microcolumnar dual-doped scintillator
CsI Film Side View
Microcolumnar CsI:Tl scintillator film
Fish radiograph made with RMD CsI-based scintillator
Radiograph of a tiny fish using one of RMD's CsI-based scintillators. Note the well defined ~50 micron wide bone structure, including the closely spaced bones in the background of soft tissue, and the air sacks.
ENLARGEMENT
Shell leaving the barrel of a tank
The unexpected and unusual (and absolutely unretouched) result of photographing samples of RMD's ZnSe:Te scintillator under 254 nm UV light, where they naturally fluoresce.
ENLARGEMENT
Imaging Technology Group at RMD

Scintillator Materials

-----Our ongoing research into advanced scintillator materials includes inorganic, semiconductor, ceramic, plastic, and hybrid scintillators, and we are constantly developing and refining novel, advanced forms of these materials for detecting X-rays, gamma-rays, neutrons, alpha particles, beta particles, protons and their combinations. We typically grow our materials using approaches beyond conventional crystal growth techniques, in either crystalline form (generally best suited to radiation detection, monitoring and energy-measurement applications) or microcolumnar form (best suited for imaging applications). We often pre- and post-process the resulting materials to the needs of targeted applications. Scintillators presently may be small and compact, up to 3 x 3 cm², suited to the requirements of applications such as dentistry, to as large as 50 x 50 cm², for large-field imaging such as chest radiography. Certain applications, such as in-flight missile/projectile X-ray imaging, require particularly sizable sensors (up to 90 x 90 cm² or larger), which we typically fabricate by tiling multiple sensors on suitable support structures. Currently in production and pilot production, our scintillators typically provide better contrast, finer resolution, greater brightness, higher sensitivity and faster performance than the imaging screens and scintillators traditionally used in radiography and in radionuclide imaging.

Our current research and development is focused on a comprehensive variety of scintillator materials and forms, including:

Co-doped inorganic scintillators, including CsI:Tl,Sm, CsI:Tl,Eu and CsI :Tl with other co-dopants. Our work has yielded important new forms of the widely used CsI:Tl scintillator, with both afterglow and hysteresis reduced to insignificant levels. We are now fabricating both crystalline and microcolumnar film forms of these materials.

Lanthanum halide scintillators, including LaBr3:Ce and LaCl3:Ce. We synthesize these materials using our proven co-evaporation vapor deposition approaches.

New bright semiconductor scintillators, including ZnSe:Te and other Group II-VI materials with various dopants. These are fabricated in microcolumnar and other forms.

Ceramic scintillators, including Lu2O3:Eu, Gd2O2S:Tb and ZnSe:Te. Up to 3" diameter, 3 mm thick transparent optical ceramics of Lu2O3 have been fabricated. This material has the highest known density among scintillators, measuring 9.59 gm/cc, and its 630 nm red emission is well suited for silicon photodetectors. Synthesis of Gd2O2S:Tb and ZnSe:Te in ceramic form is currently under way.

Neutron scintillators, including LiI:Eu, boron- or gadolinium-loaded plastic scintillators, and microcolumnar CsI:Tl sandwiched within transparent compounds containing boron (B) or gadolinium (Gd). The scintillators at the heart of these neutron sensors may be fabricated using alternate techniques, but at present the most common forms are microcolumnar film and pixelated slab.

Hybrid scintillators, consisting of layers of microcolumnar scintillator films of different materials, or films deposited on scintillating fiberoptic substrates. Hybrid scintillators may be fabricated effectively by the vapor deposition of one material atop another, in which case the columnar growth of the second material begins exactly atop the microcolumns of the first material deposited, yielding continuity in the light path and preserving spatial resolution and light conservation.

Our research and development also focuses on improving key aspects of scintillator material characteristics and performance, including:

* Light emission * Sensor size
* Imaging resolution * Economy
* Transparency * Sensitivity
* Manufacturability * Hysteresis
* Energy resolution * Hygroscopicity
* Afterglow  
* Speed of recovery after radiation exposure
* Resistance to high radiation exposure
* Matching of scintillator light emissions to photodetector sensitivities
* Performance stability under varying or unusual operational conditions
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