Scintillator Materials
-----Our
ongoing research into advanced scintillator materials
includes inorganic, semiconductor, ceramic, plastic,
and hybrid scintillators, and we are constantly developing
and refining novel, advanced forms of these materials
for detecting X-rays, gamma-rays, neutrons, alpha
particles, beta particles, protons and their combinations.
We typically grow our materials using approaches beyond
conventional crystal growth techniques, in either
crystalline form (generally best suited to radiation
detection, monitoring and energy-measurement applications)
or microcolumnar form (best suited for imaging applications).
We often pre- and post-process the resulting materials
to the needs of targeted applications. Scintillators
presently may be small and compact, up to 3 x 3 cm²,
suited to the requirements of applications such as
dentistry, to as large as 50 x 50 cm², for large-field
imaging such as chest radiography. Certain applications,
such as in-flight missile/projectile X-ray imaging,
require particularly sizable sensors (up to 90 x 90
cm² or larger), which we typically fabricate
by tiling multiple sensors on suitable support structures.
Currently in production and pilot production, our
scintillators typically provide better contrast, finer
resolution, greater brightness, higher sensitivity
and faster performance than the imaging screens and
scintillators traditionally used in radiography and
in radionuclide imaging.
Our current research and development
is focused on a comprehensive variety of scintillator
materials and forms, including:
Co-doped inorganic scintillators, including
CsI:Tl,Sm, CsI:Tl,Eu and CsI :Tl with other co-dopants.
Our work has yielded important new forms of the widely
used CsI:Tl scintillator, with both afterglow and
hysteresis reduced to insignificant levels. We are
now fabricating both crystalline and microcolumnar
film forms of these materials.
Lanthanum halide scintillators, including
LaBr3:Ce and LaCl3:Ce. We synthesize
these materials using our proven co-evaporation vapor
deposition approaches.
New bright semiconductor scintillators, including
ZnSe:Te and other Group II-VI materials with various
dopants. These are fabricated in microcolumnar and
other forms.
Ceramic scintillators, including Lu2O3:Eu,
Gd2O2S:Tb and ZnSe:Te. Up to
3" diameter, 3 mm thick transparent optical ceramics
of Lu2O3 have been fabricated.
This material has the highest known density among
scintillators, measuring 9.59 gm/cc, and its 630 nm
red emission is well suited for silicon photodetectors.
Synthesis of Gd2O2S:Tb and ZnSe:Te
in ceramic form is currently under way.
Neutron scintillators, including LiI:Eu, boron-
or gadolinium-loaded plastic scintillators, and microcolumnar
CsI:Tl sandwiched within transparent compounds containing
boron (B) or gadolinium (Gd). The scintillators at
the heart of these neutron sensors may be fabricated
using alternate techniques, but at present the most
common forms are microcolumnar film and pixelated
slab.
Hybrid scintillators, consisting of layers
of microcolumnar scintillator films of different materials,
or films deposited on scintillating fiberoptic substrates.
Hybrid scintillators may be fabricated effectively
by the vapor deposition of one material atop another,
in which case the columnar growth of the second material
begins exactly atop the microcolumns of the first
material deposited, yielding continuity in the light
path and preserving spatial resolution and light conservation.
Our research and development also focuses on improving
key aspects of scintillator material characteristics
and performance, including:
| * Light emission |
* Sensor size |
| * Imaging resolution |
* Economy |
| * Transparency |
* Sensitivity |
| * Manufacturability |
* Hysteresis |
| * Energy resolution |
* Hygroscopicity |
| * Afterglow |
|
| * Speed of recovery after radiation
exposure |
| * Resistance to high radiation exposure |
| * Matching of scintillator light
emissions to photodetector sensitivities |
| * Performance stability under varying
or unusual operational conditions |
|